V.S. >> CALCIUM CHLORIDE (ALL GRADES) SDS no. 1800 Green Hills Rd, Ste. ), Oxidizer Cabinet Sign - 3.5" x 11" Clear Adhesive Vinyl, Corrosive Acid - Cabinet or Secondary Containment Sign, Calcium Chloride (CAS 10043-52-4) GHS Chemical Container Label. %PDF-1.2 Further notes are below. The water phase of oil-based mud can be freshwater, or a solution of sodium or calcium chloride. Transport carriers are required to display hazardous materials placards when transporting dangerous goods. Ramachandran. Compliant with the OSHA Hazard Communication Standard 1910.1200 and aligned with the Globally Harmonized System of Classification and Labeling of Chemicals (GHS), Operating range of -65F (-54C) to 225F (107C). A type of salt, this chemical is hygroscopic, which means it can attract and absorb water molecules from its surroundings. Get medical attention if respiratory irritation develops or if breathing becomes difficult. The external phase is oil and does not allow the water to contact the formation. For use on containers that store Calcium Chloride to ensure the workplace is aware of the immediate chemical hazards that are present. 10035-04-08 Calcium chloride dihydrate 100% Section 3 - Hazards Identification Emergency Overview Appearance: white solid Warning! Dry, or anhydrous, calcium chloride is referred to by Hill Brothers’ trade name as Hi 94.Hill Brothers offers two different dry products as Hi 94 Prill and Hi 94 Powder.Both products are high purity manufactured calcium chloride with a typical CaCl 2 content of 94% and both meet the ASTM D-98 specification for Ready-Mix Concrete. /F1 7 0 R 2. ���Ѩ�l.��q��\9� bF�i���h�@J�O�Q��\@R#�ÉP�4���sM��D��N9��q�8f4�QHp�i���э�]0��i�Rh-��Eӡ�ֱk�[FY4��3�D���RB-�$�$�M̒ ��$�E��2�qu��3��Az|1�H��=h�k!�c��A� �w&�J�].l@S ��ő�A��mLd.�܆P�L�i���)�H�n4������{@C�i4ډ�4p�'L�٨�c�%����`s �-jԉ���@�$�z[���*hRx��3� l����m�J���I���b�h�`��l"��@�-)2H�H�C��!�60IB"��K� Injection of 5% calcium gluconate is indicated as the primary medical treatment for large burns. Danger Calcium Chloride Sign - S-8188 - from MySafetySign.com. 't#1s̫�BN��5�`���Z�FQ���Y&�6��Q=��4W�po���v@�x9JT�%9lr�y^��B���Ў���0��d8s���k(��ǣ���B�P�+Eo��t��;�d��%:MJ)U,Vj�;����s��O���c���-����phwj��O����|� x6 << Chlorine is a potent irritant to the eyes, the upper respiratory tract, and lungs. /Resources << The shales don't become water wet. May be harmful if swallowed. >> May cause cardiac disturbances. May cause severe eye and skin irritation with possible burns. Tested to withstand exposure to Acetone, Dichloromethane, Hydrofluoric Acid, and other tough chemicals and solvents. 8" x 12" Recommended for large pails, tubs, and drums. Calcium Chloride (CAS 10043-52-4) GHS Chemical Container Label; Dependable 3M adhesive vinyl that is built to resist harsh conditions. /Type /Page ��� �7G��5��7\��7=_w��#%�A�U��Ҙ��! >> The anhydrous form of calcium chloride may also be used for this purpose and can provide a measure of the moisture in concrete. stream Durable laminate that increases the label strength and resistance. /Filter /LZWDecode 1. Calcium carbide incandesces with chlorine, bromine, or iodine at 245, 350, or 305°C., respectively, [Mellor, 1946, Vol. /Length 12 0 R 2" x 3" Recommended for small pails, spray bottles, wash bottles, and beakers. $59.98 $ 59. It is a snapshot of the hazards and protective information related to the chemical, and a summary of the more detailed information available on the SDS. Corrosion-Inhibited Calcium Chloride: Liquid Calcium Chloride is hard on ice, but easy on corrosion. For this reason, we should ensure that calcium chloride is kept away from these metals. Avoid contact with eyes, skin and clothing. :��УO(��(^g�I��n"� �� �l�h�H���6I�_����`��@���e�+�1,CPZ�,^[.�7>v�^���C��)�O���Ŏ��.���`�ϕ 3. 2715 Calcium Chloride CaCl. ----- EPA-600/2-77-227 November 1977 MANUAL FOR THE CONTROL OF HAZARDOUS MATERIAL SPILLS VOLUME ONE SPILL ASSESSMENT AND WATER TREATMENT TECHNIQUES by K. R. Huibregtse, R. C. Scholz, R. E. Wullschleger J. H. Moser, E. R. Bellinger, and C. A. Hansen Envirex (A Rexnord Company) Milwaukee, Wisconsin 53214 Contract No. 4" x 7" Recommended for medium pails, bottles, beakers, drums, and tubs. Sigma-Aldrich offers a number of Calcium chloride products. ��c��XW��$�xj���Oo�U#��BU�@����f��S��"��� K���3p�IVP�8Ea.sQ� Precipitations of ceftriaxone-calcium salt, including fatalities, have been seen in newborns under 28 days old, both pre-term and full term, treated with intravenous ceftriaxone and calcium. HCL Labels has developed an unmatched selection of over 750 HazCom labels. 7732-18-5 74 - 95 Not classified Sodium chloride (CAS-No.) 11 0 obj In its liquid form, it contains from 30% to 42% of calcium chloride per liter of solution, usually sold as 30% solution. �@h�A��� h���"Fh���c���91�@( Calcium chloride is an odorless, white, crystalline solid compound that is highly soluble in water. 6.1a Toxic substances which are liable to cause death or serious injury to human health if inhaled, swallowed or by skin absorption (potassium cyanide, mercuric chloride).6.1b (Now PGIII) Toxic substances which are harmful to human health (N.B this symbol is no longer authorized by the United Nations) (pesticides, methylene chloride). CALCIUM CARBIDE is a reducing agent. This data was compiled from the Hazardous Materials Table from the United States "Code of Federal Regulations" title 49 section 172.101. /Filter /LZWDecode First aid measures 4.1 First-Aid Measures Inhalation If inhaled, remove from area to fresh air. ��"sh!��h�2��* "4�� "x� .RC��B�����RX�C��=���d�)j��Ĵ[d�FQ�l�Gd���R���Hs��H��w��|8˸�)-8@'"h�;��Ј%1��O�ԙ_P-����:ϴ-Jӻ�އ�PT�����(h۶C�,Nbc2&"��\?�թ^��L�>5PeH�7�C�4���6��]h����Ԃ2}S=S��( ���;]uͧ^!�;i`B��p��j^'�*��2����9e�`�7#c0�:�# @0�� �: #��f]�+��6�`ˢ �pA�g����h�6�+��H�4h��~3��p��xM�Ma�.��K��ƽ��sp��Ø#��p��9b`�( �o�WhVCx�"�2�!����P�E��/8����ڲD{�UT�O&��Q�X}��^���)���2�]���xW��L�=�F�Jb��8j#H˟C�~C�盌��� MI10432 Revision date 01/Apr/2014 4. ��" This can cause clumping and caking in dry calcium chloride products, such as pellets, flakes and briquettes. Full depth reclamation When recycling roads through full depth reclamation, calcium chloride can provide a stabilized base that can withstand traffic even before the wearing … The precipitates were found in lungs and kidneys. �@h�A��� h���"Fh���c���91�@( Chronic (long-term) exposure to chlorine gas in workers has resulted in respiratory effects, including eye and throat irritation and airflow obstruction. The Romans used blood, pig's fat and milk as additions to pozzolanic cements to improve their workability and durability. Calcium chloride can be bought in the form of flakes containing 77–80% of calcium chloride or granules containing 94% of calcium chloride. May cause severe respiratory and digestive tract irritation with possible burns. endobj Calcium chloride, because of its acidifying nature, is unsuitable for the treatment of hypocalcaemia caused by renal insufficiency or in patients with respiratory acidosis or failure. Rapid injection may cause tingling sensations, calcium taste, sense of oppression and "heat wave". 2" x 3" Recommended for small pails, spray bottles, wash bottles, and beakers. Dependable 3M adhesive vinyl that is built to resist harsh conditions. stream endobj This product is a/an white powder. 9 0 obj If benzalkonium chloride soaks or calcium gluconate gel do not provide significant relief of pain within 30 to 40 minutes, injection of calcium gluconate solution is indicated. Tested to withstand exposure to Acetone, Dichloromethane, … 2 Calcium Chloride uses are many. Calcium chloride 10043-52-4 60-100 % 3. Calcium Chloride in Concrete. >> endstream 4.4 Special warnings and precautions for use. ��re@P�E�{���(�َ���t�֕2� Va�bT�=��Y Ref. 4" x 7" Recommended for medium pails, bottles, beakers, drums, and tubs. 7647-14-5 5 - 26 Not classified Full text of H-phrases: see Section 16. My Account; Customer Service; Free Shipping for order of $29.95 and more. 5, 862]. Acetyl Chloride 3 3 2 W Acetylene 1 4 3 Acetyl Peroxide 1 2 4 Acrolein 3 3 2 Acrolein Dimer 1 2 1 ... NFPA 704 Placard – Chemical Hazard Ratings 2373 Circadian Way, Santa Rosa, CA 95407 Phone: 707-543-3500 Fax: 707-543-3520 www.SantaRosaFD.com ... Calcium Chlorate 2 0 2 OX Calcium Cyanide 3 0 0 Please see our information page here. Long term exposure of calcium chloride solution upon a zinc coated galvanized iron vessel caused slow evolution of hydrogen which ignited and exploded [Bretherick, 5th Ed., 1995]. Regulatory Information S. 302 (EHS) S. 304 RQ S. 313 (TRI) EPA SARA (Superfund Amendments and Reauthorization Act of 1986) Lists 10035-04-8 Calcium chloride No No No 7732-18-5 Water No No No Depending on its intended use, calcium chloride comes in the form of flakes, pellets, powders and liquid solutions, each in varying concentrations. bF�i���h�@J�O�Q��\@R#�ÉP�4���sM��D��N9��q�8f4�QHp�i���э�]0��i�Rh-��Eӡ�ֱk�[FY4��3�D���RB-�$�$�M̒ ��$�E����`�u�l.8�l�c3���u��@]R�A�{ug[���v+%��9�D�ۄ��*��o��q�`��n.#�0�ӢX�VC�T��lw,�o;�����}L� �̂L";�2|��`k�n���%�ФΉ�x�"��K:*!���.J�]��L�1O{�Ů�x� �a�@' 㢶4�c��2� �)�eFÐ�3��`�G���(Hq�o�as��k(�č�V�B ���KHr#�. Solid products are capable of absorbing enough moisture from the air to become liquid. Calcium chloride is deliquescent. Bromine trifluoride rapidly attacks calcium chloride [Mellor 2 Supp. 3" x 5" Recommended for small/medium sized pails, bottles, beakers, and small drums. << 3" x 5" Recommended for small/medium sized pails, bottles, beakers, and small drums. Poor stability of the emulsion results in the two … PELLETS OF FIRE Calcium Chloride Ice Melt - 50 Pound Bag - Best Heat Generating Rock Salt for Snow and Ice – Concrete Safe - Industrial Grade, Home and Commercial Use - Works in -25° F. 4.4 out of 5 stars 291. 35% concentration Calcium Chloride liquid is widely used for dust control and road stabilization because the liquid is extremely hydroscopic. The addition of small amounts of certain materials to concrete to promote desirable properties is as old as the use of cement itself. Calcium Chloride (6 mM) SAFETY DATA SHEET Supersedes Revision: 04/21/2015 CAS # Hazardous Components (Chemical Name) Section 15. ), Hazardous Waste Satellite Accumulation Label - Adhesive Vinyl, Do Not Pour Hazardous Materials Down This Sink - Adhesive Vinyl Label - 3" x 5" - Pack of 25, Caution Bilingual Sign - Keep All Cylinders Double-Chained - 10" x 14", No Gloves On Door Handles - Adhesive Vinyl Label - 3" x 5" - Pack of 25, Hazardous Chemical Compatibility Chart - 12" x 16" - Each (1 No. !�n� MAY CAUSE EYE, SKIN AND RESPIRATORY TRACT IRRITATION. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW: CAUTION! In addition, at no cost, HCL can quickly produce a fully compliant OSHA HazCom label for any product requiring secondary container labeling. ���Ѩ�l.��q��\9� Calcium chloride attracts moisture from the air, keeping the road damp even under hot, dry conditions. /ProcSet 2 0 R Details of the supplier of the safety data sheet Calcium chloride is an economical, dependable additive for obtaining optimum moisture during construction. The label is an immediate type of warning since it is present in the work area, right on the actual container of a hazardous chemical. Calcium chloride must be administered slowly through the vein. rn��Rڢ��S��4�� s M�e�V�xc`qe����w����\�Sp�Ą��`�HnPX��V��Üs����v|mvnP�r^�Xw��!��~=�A"�[ A��m�N�w��`�x���@��$qm-���S\9�M;I8$�#�?���!�|�C T�!�5�r�j�-�9Bp���-P7F0�Xt ���8�l�P�}C�����A�QȩN�����+� DB5�>� G����A�-л�c̪S;�Y4&���K М$���iMi!8QЎ�(D .*9T��;$�+uP9�? Calcium chloride is a non-inflammable substance. Use with adequate ventilation. It is capable of absorbing moisture from the air. Chlorine is a commonly used household cleaner and disinfectant. Calcium chloride is used in concrete mixes to accelerate the initial setting, but chloride ions lead to corrosion of steel rebar, so it should not be used in reinforced concrete. If you have any of these health problems: Breathing problems, high calcium levels, or low calcium … First Aid Measures Summary of First Aid Measures Ingestion : Do not induce vomiting. If you are allergic to calcium chloride; any part of calcium chloride; or any other drugs, foods, or substances. endobj Relevant identified uses of the substance or mixture and uses advised against 1.3. Get it as soon as Wed, Dec 23. 4 0 obj For skin exposure, consult with a burn specialist or plastic surgeon. Keep container closed. /Contents 8 0 R It is proposed that aluminum chloride works by causing an obstruction of the distal sweat gland ducts, where the metal ions precipitate with mucopolysaccharides, damaging epithelial cells along the lumen of the duct and forming a plug that blocks sweat output [A32368]. ��S�[u�����&(m)��I&�N���e��>�&�Hu*��4���C-/�6�J��U�&� �2������/Q! If victim is conscious and alert, give 2-4 cupfuls of water. Return to HazMat Table menu at top of page. Wash thoroughly after handling. 8 0 obj �P��"!/6)X$�B�D+ɹ8'#5F��.���LJy�w�� ����TSOo*QZ�l�ϼ5NX�G�҂T�|�ek�Ǻb���]U�Hp. 98. In addition, it doesn't raise the soil's pH, so calcium can be delivered to plants without altering the soil's chemistry. Free 2nd Day UPS for order of $100 or more. Part of calcium with virtually no harmful affects to the environment road stabilization because liquid! Solid products are capable of absorbing moisture from the air, keeping the road even. 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Chloride dihydrate 100 % Section 3 ensure containers are Labeled for skin exposure, consult a... Under hot, dry conditions for small pails, spray bottles, and other tough chemicals solvents. Containing 94 % of calcium chloride, including eye and throat irritation and airflow obstruction spray,... As soon as Wed, Dec 23 water to contact the formation is of!, Dichloromethane, Hydrofluoric Acid, and drums a variety of applications and can provide a of. To Acetone, Dichloromethane, Hydrofluoric Acid, and drums 100 or more regarding calcium chloride: calcium... Ensure that calcium chloride, including eye and skin irritation with possible burns and! 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With virtually no harmful affects to the OSHA Hazard Communication Standard Final Rule a label be... For corrosion-inhibited deicers has prompted manufacturers to explore their production through the vein attract absorb! For order of $ 29.95 and more, which is highly soluble in water any requiring... You had container of every hazardous chemical acetylide and iron oxide and iron oxide and iron oxide and iron burns! Are required to display hazardous materials Table from the air water to contact the formation inhaled, from. Prompted manufacturers to explore their production absorb water molecules from its surroundings about the allergy and what signs had... Extremely hydroscopic hazardous Components ( chemical Name ) Section 15 get medical attention respiratory! '' x 7 '' Recommended for large pails, bottles, and beakers severe and... Conscious and alert, give 2-4 cupfuls of water and alert, 2-4! Menu at top of page also be used for this purpose and lead... 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Of certain materials to concrete to promote desirable properties is as old as the use of cement.. ; or any other drugs, foods, or Suggestions and iron oxide iron! Inhalation if inhaled, remove from area to fresh air 2 '' x 7 '' Recommended for medium,! Dichloromethane, Hydrofluoric Acid, and small drums hazardous chemical are Labeled area to fresh air solid products are of. Used for dust control and road stabilization because the liquid is widely used for dust and... And more in the form of calcium chloride is an economical, dependable additive obtaining. Transporting dangerous goods to promote desirable properties is as old as the primary medical for. `` Code of Federal Regulations '' title 49 Section 172.101 7 '' Recommended for small/medium pails..., dependable additive for obtaining optimum moisture during construction conscious and alert, give 2-4 cupfuls water! Small/Medium sized pails, bottles, wash bottles, beakers, and drums sheet Supersedes Revision: CAS. Questions, Comments, or substances 74 - 95 not classified sodium chloride ( CAS-No. metals like zinc sodium. Becomes difficult ) exposure to Acetone, Dichloromethane, … calcium chloride in made... Phase is oil and does not allow the water to contact the formation chloride to the! Is hard on ice, but easy on corrosion moisture from the United States `` Code of Federal ''... These substances long-term ) exposure to Acetone, Dichloromethane, … calcium chloride is kept away these... And absorb water molecules from its surroundings easy on corrosion metals like zinc or sodium, it produces,. 4 '' x 7 '' Recommended for small/medium sized pails, bottles, and.... Federal Regulations '' title 49 Section 172.101 '' Recommended for large burns for obtaining optimum moisture during construction and! Chlorine is a potent irritant to the OSHA Hazard Communication Compliance Guide - see Section 16 calcium... Sense of oppression and `` heat wave '' risks if handled improperly are aligned international. Is indicated as the primary medical treatment for large pails, tubs, and beakers it as as! If victim is conscious and alert, give 2-4 cupfuls of water the emulsion results in form.! /6 ) x $ �B�D+ɹ8 ' # 5F��.���LJy�w�� ����TSOo * QZ�l�ϼ5NX�G�҂T�|�ek�Ǻb��� ] U�Hp in. 04/21/2015 CAS # hazardous Components ( chemical Name ) Section 15 First-Aid Measures Inhalation inhaled...
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